The characteristics of an adaptive test change the characteristics of the field testing that is necessary to add items to an existing measurement scale. The process used to add field-test items to the adaptive test might lead to scale drift or disrupt the test by administering items of inappropriate difficulty. The current study makes use of the transitivity of examinee and item in item response theory to describe a process for adaptive item calibration. In this process an item is successively administered to examinees whose ability levels match the performance of a given field-test item. By treating the item as if it were taking an adaptive test, examinees can be selected who provide the most information about the item at its momentary difficulty level. This should provide a more efficient procedure for estimating item parameters. The process is described within the context of the one-parameter logistic IRT model. The process is then simulated to identify whether it can be more accurate and efficient than random presentation of field-test items to examinees. Results indicated that adaptive item calibration might provide a viable approach to item calibration within the context of an adaptive test. It might be most useful for expanding item pools in settings with small sample sizes or needs for large numbers of items.